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Neutral Organic Radical Formation by Chemisorption on Metal Surfaces

Área de investigaciónQuímica y Ciencia y Tecnología de los Materiales
TítuloNeutral Organic Radical Formation by Chemisorption on Metal Surfaces
Tipo de publicaciónArtículo de revista
Año de publicación2020
AutoresAjayakumar, M. R., C. Moreno, I. Alcon, F. Illas, C. Rovira, J. Veciana, S. T. Bromley, A. Mugarza, y M. Mas-Torrent
RevistaJOURNAL OF PHYSICAL CHEMISTRY LETTERS
Volumen11
Número10
Páginas3897-3904
Type of ArticleArticle
Abstract

Organic radical monolayers (r-MLs) bonded to metal surfaces are potential materials for the development of molecular (spin)electronics. Typically, stable radicals bearing surface anchoring groups are used to generate r-MLs. Following a recent theoretical proposal based on a model system, we report the first experimental realization of a metal surface-induced r-ML, where a rationally chosen closed-shell precursor 3,5-dichloro-4-{[}bis(2,4,6-trichlorophenyl) methylen]cyclohexa-2,5-dien-1-one (1) transforms into a stable neutral open-shell species (1(center dot)) via chemisorption on the Ag(111) surface. X-ray photoelectron spectroscopy reveals that the >C=O group of 1 reacts with the surface, forming a C-O-Ag linkage that induces an electronic rearrangement that transforms 1 to 1(center dot). We further show that surface reactivity is an important factor in this process whereby Au(111) is inert towards 1, whereas the Cu(111) surface leads to dehalogenation reactions. The radical nature of the Ag(111)-bound monolayer was further confirmed by angle-resolved photoelectron spectroscopy and electronic structure calculations, which provide evidence of the emergence of the singly occupied molecular orbital (SOMO) of 1(center dot).

DOI10.1021/acs.jpclett.0c00269