Área de investigación | Química y Ciencia y Tecnología de los Materiales |
Título | A flexible self-folding receptor for coronene |
Tipo de publicación | Artículo de revista |
Año de publicación | 2019 |
Autores | Lozano, D, Álvarez-Yebra, R, López-Coll, R, Lledó, A |
Revista | Chem. Sci. |
Volumen | 10 |
Páginas | 10351-10355 |
Abstract | We report a conformationally flexible deep cavitand receptor based on calix[5]arene and stabilized by a cooperative network of hydrogen bonds. The receptor binds coronene selectively over smaller polycyclic aromatic hydrocarbons{,} but is flexible enough to adapt to a smaller guest that presents a complementary electron deficient surface. The unique dynamic properties of this system have been thoroughly studied by NMR spectroscopy and molecular dynamics (MD) simulations. |
DOI | 10.1039/C9SC03158H |